Atlas of Stereochemistry: Absolute Configurations of Organic by J. Buckingham, R. A. Hill (auth.)

By J. Buckingham, R. A. Hill (auth.)

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Hyl- 6(7- btnzomorphan(R • Mo) . IR,5S)2cycIobulylmothyl- 5- olhyl -2'hyd,oxy-9, 9-dimothyl-6, 7btnzomorphan(R : CH 2 C4 H 7 ) . Abs. X-roys [7](" lS. (RH-) 4-(dilsopropylomino )-2(2-pyridyl)- 2 - phonylbulyromido . RM. X-roy 01 biloruolt ,all. 6 . _ . (40S, IObR)-(-) 4 ' methyl - IOb · I I 1 i methoxycorboxyloctohydrobeozo . [f] quonol,ne Ab • . X'roy [8] . I I 15( S)-(- )1,2 - d,methyl cycJopent-2-ene-lcorboJl;yhc aCid. 5- ep;mer (-). tThis compd. shows solvent-dependent opt. rotn. 21 appears to be correct [1 J.

Diversi and G. Ingrosso, Gazz. Chirn. , 1968, 98, 1391. S. Mitsui and S. Imaizumi, Nippon Kagaku Zasshi , 1965, 86, 219; CA, 63, 4133f. W. Kirmse and W. Gruber, Chern. , 1971, 104, 1795. A. Garbarino and O. Nunez, J. Chern. , Perkin Trans. 1, 1981 , 906. S . S. Portoghese, J. Med. , 1976, 19, 1155. See p. A5l. R. Ahmed and M. , Sect. B, 1979, 35, 2169. G. J. De Ranter and H. Schenk, Acta Crystallogr. , Sect. B , 1979, 35, 699. K. M. Carlson, J. Arn. Chern. , 1965, 87, 2772. 47 (SH+) S 'phenyl hexonoie oeid A'20.

Ehern. , 1963, 85, 2295. L. S. Kantner, 1. Org. , 1981, 46, 4605. E. E. Gilbert, J. Am. ehern. , 1976, 98, 8283. A. A. Beavers, J. Am. ehern. , 1771, 93, 2677. A. G. M. Clarke and D. Wege, J. Am. ehern. , 1969, 91, 5601. M. Nakuzaki, H. Chikamatsu, T. Fujii and T. Nakutsuji, 1. Org. , 1981, 46, 585. H. M. Dekkers, J. ehern. , Perkin Trans. 2, 1982, 1429. 2. 3. 4. 5. 6. 7. 8. 40 ! H 11. 1. no . q::r o H 15 . (l5,4SH 1bicyclo(4 . 0]OO-3-ono2,7-dion • . A39" Class 3a CH2COOH C~I c(O H3C + H (fO] H3C + H CH2 COOMe (R)-(+) mornyl nydr090n 1.

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