By Olaf Kuhl(auth.)
N-heterocyclic carbenes (NHCs) have stumbled on expanding use as reagents for more than a few natural variations and in uneven organocatalysis. The functionality of those molecules will be more advantageous and tuned through functionalisation. Functionalised carbenes can anchor unfastened carbenes to the steel web site, introduce hemilability, offer a way to immobilise transition steel carbene catalysts, introduce chirality, offer a chelate ligand or bridge steel centres. NHC will be hooked up to carbohydrates and campher, derived from amino acids and purines, they are often used as organocatalysts mimicking nutrition B1 or as susceptible “solvent” donors in lanthanide chemistry.
Functionalised N-Heterocyclic Carbene Complexes describes significant traits in functionalised NHC ligands, aiming to help readers of their makes an attempt to enhance and observe their very own functionalised carbenes. After an advent to the chemistry and behavior of NHC, the publication offers an in depth description of functionalised carbenes and their complexes based on a number of practical teams, every one with a dialogue of the factitious direction, constitution, balance and function.
Functionalised N-Heterocyclic Carbene Complexes is an important consultant to fine-tuning this crucial type of compounds for practitioners, researchers and complex scholars operating in artificial organometallic and natural chemistry and catalysis.Content:
Chapter 1 the character of N?Heterocyclic Carbenes (pages 7–37):
Chapter 2 Why Functionalisation? (pages 39–53):
Chapter three N?Heterocyclic Carbenes with impartial Tethers (pages 55–197):
Chapter four N?Heterocyclic Carbenes with Anionic useful teams (pages 199–278):
Chapter five Chiral N?Heterocyclic Carbenes (pages 279–308):
Chapter 6 common items (pages 309–345):
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Extra info for Functionalised N-Heterocyclic Carbene Complexes
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