Organic Reaction Mechanisms 1971 by B.; Rees, C.W. (editors) Capon

By B.; Rees, C.W. (editors) Capon

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S. Newman and C. D. Beard, J. Am. Chem. ,92, 7564 (1970). 265 A. F. Hegarty, M. Cashman, J. B. Aylward, and F. L. Scott, J. Chem. (B), 1971, 1879. 266 N. C. Den0 and P. C. Scholl, J. Am. Chem. ,93,2702 (1971). 2~37D. M. Brouwer and J. A. van Doorn, Rec. Trav. , 90,535 (1971). ass H. Hogeveen and C. F. Roobeck, Rec. Trav. , 89, 1121 (1970). 280 J. Lukas and H. Hogeveen, Chem. , 104,2964 (1971). 2134M. 272 13C NMR spectra of para-substituted triphenylmethanols have been interpreted in terms of charge densities; results are in accord with simple resonance picture with relative large positive charges at positions a and meta to the substituent.

Sahatjian, J . Orgunomel. , 25, C67 (1970). Zo2 B. T. Golding, H. L. Holland, U. Horn, and S. Salrrikar, Angew. Chem. Int. , 9, 959 (1970). 195 Carbonium Ions 37 PY (155) R =CH~CHBOCOCH~ R =CH&H(OCOCH3)CH3 Strongly basic amines react with tricarbonyl(syn,sylz-l,5-dimethylpentadieny1)iron carbonium ion to give the tricarbonyl(cis,trans-dieny1amine)ironcomplexes by exoattack of nucleophile on the coordinated pentadienyl group. 206 Neighbouring-group participation and ring expansion have been observed on formation of the tricarbonyl-(l-methylcyclohexadieny1)ironcarbonium ion (159) on heterolysis of tricarbonyl-[5-endo-methyl-5-ezo-( tosyloxymethyl)cyclopentadiene]iron ( 158) in (CH3CO)zO/aq.

Derendyaev, V. I. Mamatyuk, and V. A. Koptyug, J . Org. Chem. U S S R ,6,2074 (1970). 116 R. K. Lustgarten, M. Brookhart, and S. Winstein, Tetrahedron Letters, 1971, 141. 1]oct-6-en8-yl toluene-p-sulphonate in acetic acid and ethanol-water mixtures. Product of retained configuration was obtained and the rate of solvolysis was ca. 105 times faster than for the saturated analogue. 121 The rate 3f solvolysis was 3 x l o 4 times faster than for the saturated analogue, and the product acetate had completely retained configuration.

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